The products of the pyrolysis reactions of perfluoropropane, perfluoroethane, and carbon tetrafluoride in an Inconel bomb are described. The values for the energy of activation and frequency factor for the first-order pyrolysis reactions are respectively: (1) 80 kcal. per mole and 2x10(exp14) sec.(exp-1) for perfluoropropane; (2) 53 kcal. per mole and 3x10(exp7) sec.(exp-1) for perfluoroethane; and (3) 96 kcal. per mole and 4x10(exp13) sec.(exp-1) for carbon tetrafluoride.