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IN THE UNITED STATES PATENT AND TRADEMARK OFFICE 



In re Patent Application of 
Applicants: Bednorz et al. 
Serial No.: 08/479,810 
Filed: June 7, 1995 



Date: May 15, 2008 



Docket: YO987-074BZ 



Group Art Unit: 1751 
Examiner: M. Kopec 



For: NEW SUPERCONDUCTIVE COMPOUNDS HAVING HIGH TRANSITION 

TEMPERATURE, METHODS FOR THEIR USE AND PREPARATION 
Commissioner for Patents 
United States Patent and Trademark Office 
P.O. Box 1450 
Alexandria, VA 22313-1450 



VOLUME 4 
Part 2 

BRIEF ATTACHMENTS D TO E 



Respectfully submitted, 



/Daniel P Morris/ 

Dr. Daniel P. Morris, Esq. 
Reg. No. 32,053 
(914) 945-3217 



APPEAL BRIEF 
PART IX 



CFR 37 §41 .37(c) (1) (ix) 



SECTION 1 



IBM CORPORATION 
Intellectual Property Law Dept. 
P.O. Box 218 

Yorktown Heights, New York 10598 



BRIEF ATTACHMENT D 





IN THE UNITED STATES PATENT AND TRADEMARK OFFICE 



In re Patent Application of 
Applicants: Bednorz et al. 
Serial No.: 08/479,810 
Filed: June 7, 1995 



Date: March 1,2005 
Docket: YO987-074BZ 
Group Art Unit: 1751 
Examiner: M. Kopec 



For: NEW SUPERCONDUCTIVE COMPOUNDS HAVING HIGH TRANSITION 
TEMPERATURE, METHODS FOR THEIR USE AND PREPARATION 



Commissioner for Patents 
P.O. Box 1450 
Alexandria, VA 22313-1450 



In response to the Office Action dated July 28, 2004, please consider the 
following: 



FIRST SUPPLEMENTAL AMENDMENT 



Sir: 



ATTACHMENT D 



Serial No.: 08/479,810 



Page 1 of 5 



Docket: YO987-074BZ 



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13.2. Alumina powder characteristics, X-Ray data and sintering behavior 



Sample size 


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BRIEF ATTACHMENT E 



IN THE UNITED STATES PATENT AND TRADEMARK OFFICE 



In re Patent Application of 
Applicants: Bednorz et al. 
Serial No.: 08/479,810 
Filed: June 7, 1995 



Date: March 1, 2005 
Docket: YO987-074BZ 
Group Art Unit: 1751 
Examiner: M. Kopec 



For: NEW SUPERCONDUCTIVE COMPOUNDS HAVING HIGH TRANSITION 
TEMPERATURE, METHODS FOR THEIR USE AND PREPARATION 



Commissioner for Patents 
P.O. Box 1450 
Alexandria, VA 22313-1450 



In response to the Office Action dated July 28, 2004, please consider the 
following: 



FIRST SUPPLEMENTAL AMENDMENT 



Sir: 



ATTACHMENT E 



Serial No.: 08/479,810 



Page 1 of 5 



Docket: YO987-074BZ 



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Arrangement 
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Ordered 
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0.05 
0.46 

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Diiference 
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Refer- 
ences 


4, 54 






h iooo - -< o "I 

CO TfTHO H raiOrJ 














Remarks 


orthorhombio 
monoolinio, 


pseudocubic 
orthorhombio 
orthorhombio 
orthorhombio 
orthorhombio 
orthorhombio 


or oubio 
orthorhombio 
pseudooubio 
orthorhombio 
orthorhombio 


orthorhombio 

pseudotetrago; 

tetragonal 

tetragonal 

pseudooubio, 

orthorhombi 
orthorhombio 


orthorhombio 

orthorhombio 
oubio 

pseudooubio 
oubio 

orthorhombio 
orthorhombio 
oubio 




1 










" — - — 














7.884 


7.645 
8.29 
7.647 
8.008 


6.577 
7.606 


8.631 


id od co 












S 8 g 




6.518 
8.74 


6.381 
6.78 
6.326 
6.687 
7.65 


6.547 
8.74 
6.301 

3.897 


8.64 
7.62 

7.86 
3.896 
9.28 

6.986 
7.725 
3.869 


4.069 } 
8.138 J 
3.9761 
6.864 

4.0334 

8.070 

8.84 

3.904 

6.01 

5.792 1 

8.218 J 


Compound 


°*i 

oo 


CaTiO, 
CaUO, 
CaVO, 
CaZrO, 
CdCeO, 


to Eh H N H O O H E-< N o £ 


SrHfO, 

SrMoO, 
SrPbO, 
SrRuO, 
SrSnO, 

SrTiO,' 
SrUO, 
SrZrO, 



Refer- 


29 
29 

30, 31 

4, 31, 
32, 33, 
34 
36 

31, 36, 
37 

35, 38 

2, 31 

4, 40, 
41 


1 


1 * « | 

Ut 11 ?? 

S3 . .CH. 11 . 21 

H!i?l! Ill 1* 




7.888 
3.931 

6.7203 

3.886 
6.6239 




16.660 
3.914 

5.6946 

6.677 
5.4778 




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Refer- 


20, 23 
20, 22 


d 
« 


101 

101 
102 

103 

94 

18 
104 
94 

25, 102 
103 
105 

26, 102 
103 

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104 
26, 102 
103 


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< 


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6.951 














5.66 
6.664 


8.630 

8.668 

4.293 
8.800 

4.06 

8.086 

7.88 
8.437 

8.740 

8.545 

8.427 

8.716 

8.354 

8.423 

8.67 

8.507 

8.783 


Compound 


9, 6 

i i 

i i 


£ d £0 d d 0 "o"2. dddodd 0 »£o 

i i ii i i Mi i i i i i i 4 i i 

i i ii £ i Hi iiiiiiiii 

m m «n « « mmm ««««««««« 



i s 



og d d dd£ d d &do 0 " do 

WSM 11 il i I #t 4 4 III 3 Ii 

fHiili i J || | i m 4 4 Hi i a 



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fa £ fa 2 fa £ fa £ fa 2 fa £ fa 2 fa £ fa,° £ fa £ fa £ - „ fa £ fa 2 fa 2 fa £ fa £ 
fa.|fa| faffa-gfaf fa| fa| fa|fa| fa-gfa-gcO fa3fa|fa|fa|fa| 
2 g "ig^e-S? ^ 2 ^2 ^2^2 Sit! -^p'^P'Sp'Sp'S? 



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S t§ t§. (§.>§. d d 



* o oj" o^" o o« g o >- o,-* o S o 2 | S I 3 Ijo ■Solo'gS =3 

0S||ng|iiSiiEDSiiE5»g|iiSiiaaEDSiiSiifiiiaiiSDBiiBHg 



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0 oOO o"% £ ° O OO 2. O O O ^ 0 - O o 2. o 

1 ||ci ?l ^ 1 1 1| II i i i li 2 i I i i 

d d£d do. a £ & £.£ ££. § ! § w i i i i | g 

5 OOO OU A rl rl rTrl i?r1 £ # /? X X X X A A A 



Refer- 
ences 


104 

106° 2 ' 

103 
105, 106 
102 

103 

108 

25, 102 

103 

105 
102, 106 

103 

18 

105, 106 

104. 

25,96, 
102 

103 

96, 105 

109 

109 
94 
28 


1 
1 


Sill M £153 i% I* i %§%§5i%i«Si ^i^i-^-lse 
^f*! %i ^f^l^l^lM *J*Jh£*J*J £A&J°Zz%zH 

gigs gi gigigigigi gigigigigi j?ij?«7hl|| 




3.81 
3.81 
7.73 




3.80 

3.80 

5.43 
7.70 




.8.49 
8.518 

8.792 

8.519 
4.229 
8.763 

8.42 

8.408 

8.692 

8.406 

4.200 
8.718 

8.372 

8.433 

8.69 

8.374 

8.678 

8.390 

3.81 

3.81 

5.60 
5.49 


Compoiuid 


o o o" oo°o - o o" o" « „ 6 0 " o - 

2 r? « sia' i £ ^ « 1 1 ^ i g g 1 1 "= 2 

5 1 * *m 4 2 1 H 3 %£ i £ 4 1 4 4 g 4 

| I 1 IfcH ff H H |. >f >f >f £ £ £ 4 4 Sd 

mm £ m mm mmmmm^mmmm mmdcS^d 



rv. -o rr-. r T . .5 iv. H . r r . -*s r T . 5 « rv. ^ r-r. ^ rr 



g"Ig : iff fl fi f If fifff il» : lgi|l g : l 



S"5S*!§*I|"5 it 



O O 



0 0 " °0'00 O o O £0 O oOOq'o" o 



d d d dd ^" 0 "°-'° 0 -'° 0 - of -'° 0 -°- ?0 



*• '■'E'm V ut*C ^uT "iT "tT 
co co co CO co co 00 co 00 



9 llfiJ J i I If 



co m 



Refer- 
enoes 


109 
94 

109 

109 
18 

109 

109 

109 

109 

109 

109 

109 

109 
26, 110 
26 

111 

111 

111 

111 
26, 112 
26, 112 
96, 111, 

112 
96, 111 
94 

94 
94, 107 


1 
1 


^lislsliglsl^lslslslbl^l mi gig I 
sl1s§s§1s§g§s§g§g§s§§§g§ fill 5f%f 

ia|iflia|ifliSi8 1818181818 gggj "~ g 1 g 1 

«a.o«a.<»a.o«a.«a.«a.<Ja.«cL. <jq.«q.<icl B 8 8 -§ 5-5. 




4.05 

7.70 
4.06 

4.06 

5.63 
4.04 

4.05 

4.03 

4.03 

4.03 

4.03 

4.01 

4.01 

4.106 
4.098 
4.107 
4.083 




4.05 

5.40 
4.05 

4.05 

7.86 
4.04 

4.04 

4.03 

4.03 

4.02 

4.02 

4.00 

4.00 


0 


4.05 
5.55 

4.06 

5.49 
4.04 

4.05 

4.03 

4.03 

4.03 

4.03 

4.01 

4.01 

4.017 
4.011 
4.11 
4.160 
4.152 
4.163 
4.078 
4.072 
4.16 

4.13 
3.93 
7.88 

7.82 

3.9421 


Compound 


% o"o o o"S © % o o Q - o o oo'ogooooS o 0 - o . 6 Q - 

OOOOOOOOOOOOO £££££££££ & & 



Refer- 
ences 


16, 107 

17 

17 
18, 116 

17 

15 

18 
18, 115 
108, 116 

17 

15, 10 

18, 115 

17 
107 

18, 115 

17 

15, 107 
117 
18 
18, 115 

17 

16 

18 


1 
§ 


■si's jh's i5§lii%g*S i a§%i l -3§--3 is § •a-aSi'aStfS 

|l|||g : lil|lil|i|l|l|lg : igi |l|lg : | ff|lg : Igf 




8.84 

8.72 
8.29 








8.098 

8.297 

8.18 
8.05 

8.312 

8.133 

8.08 

8.082 

8.13 

8.381 

8.099 

8.18 

8.62 

4.0225 
8.04 

8.336 

8.066 

8.43 
8.60 
8.84 

8.5 

8.095 


Compound 


i £ ii i i i i i i i i i ii 4 i AiJ£ i i 
s a° l&° &° 1 I 1 I I t I 1 ^ E g &£££ 4. i 

m m mm mmmmmmmmm mm m m mmmm m m 



Refer- 




1 
1 


liiil 
II 1 ! 1 




7.99 




5.56 


•< 

e 


5.77 
8.02 

8.02 


Compound 


°o o 

ii i Mi 



ill 1 ! 1 ! 1 ! 1 ! 1 ! 1 ! 1 ! 1 ! 1 ! 1 ! P! 1 



x^o o X o 

qtf p € I o 
<? <? d ° | J 

mmm moo 

mmm mmm 



2. ;o£o 

3 o o o 
m mmm 



is 



iMiifflf 1 1 SI si I €1 si s'l s 1 1 1 s| i 



•3 a S'S g-3-3 ' 

Si S g 'S § §> §> 



So" S2. 
06 S£ 



° °»>; d o o g o; dd^ o- o 0 . 0 - o . o . o" 0 - 

£ Stat ! ! I I | ggg g g^si 
& &&&& & & & & & & &&&&& 



Refer- 


S t- .ooooo ooooooo- «° 2 


Remarks 


(NHJ.FeF, 
atruoture 
(NH<),FeF, 
structure 
(NH 4 ) a FeF, 
structure 
orthorhombio 
orthorhombio 
(NH 4 ),FeF, 
structure 
orthorhombio 
orthorhombio 
orthorhombio 
orthorhombio 
orthorhombio 
(NH«),FeF, 
structure 
orthorhombio 
orthorhombio 
(NH 4 ),FeF, 
structure 

(5 = 90°57' 

(NH,) 3 FeF e 
structure 

(NH,),FeF, 
structure 
orthorhombio 
orthorhombio 
(NH 4 )„FeF, 
structure 
orthorhombio 
orthorhombio 

tetragonal 
tetragonal 

structure 


•< 


6.80 
5.78 

5.77 
5.69 
6.58 
1 5.53 
6.56 

5.55 
6.65 

4.150 

5.85 
5.93 

5.81 

i.91 

1.9764 

r.92 

'.98 


■< 


7.87 
8.05 

7.99 
7.70 
7.71 
7.69 
7.77 

7.82 
7.67 

4.101 

8.21 1 
8.46 I 

8.16 f 
8.42 £ 


•< 

0 


8.106 

8.397 

8.116 

6.73 
5.67 
8.0 

6.64 
6.47 
5.46 
5.41 
5.48 
7.7 

5.62 
5.45 
8.1 

4.150 

7.99 

4.0 

8.21 

5.76 
6.06 
8.2 

5.73 
6.03 
3.9367 
.7.86 
7.88 
8.19 


Compound 


i i i iiiiii i%o mi i$6 d 0 - 0 - o 0 -d 0 - 0 - 0 - 
1 i * Hi iiiiii ¥£ Hi 4M 121313 

w m « ooc oooooo ooo ££££ 







Il 




Remarks 




■< 










2 © 






Compound 


So 

■is 
li 



1^1 g go o 

° +:> 3 £ o3 > 



^ ^, on « -S © 

g -3 <« P «* - - ' 
■h ° 2 § fi . 

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•2 1 1 
i ' 

s : 



§ _§ .a o g g l r 1 

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o o § sl §2*1 



50 1> 
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11 



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8 ft 



II 13 TJ 

* c I 
§ 2 "? § "S a, 

S « 05 ta £ 2 
sjf " £2 

o i? o 8 5 o 
[j t, oo d 

§1-2 2 |i 
a o s 3 ? w 

4 f 1 1 i S ^ 
£ o ^ 5 s § 1 

^11 a gl ? 

^ o p % o ^ 



si; 



Total 
Madelung 
energy 


8235 
8244 
8289 
8260 
8896 
8945 
8934 
8911 
8941 
8531 
8468 
8878 


elung 
jrgy 


0)<*t-l0l-O0>00OM0>lO 
rji-<*<<*Tfooc»aoooo3c0iooo 


Mad 
ordi 


VJ IO IO lO «3 O W lO lO lO O lO 


Madelung 
constant 


63.70 
53.70 
63.68 
62.43 
62.78 
62.94 
62.87 
57.87 
62.85 
53.46 
63.62 
62.74 




0.963 
0.963 
0.964 
1.034 
1.013 
1.004 
1.008 
1.008 
1.009 
0.976 
0.967 
1.015 


Compound 


9 ° 9* do odd o -q-cT 



' " " s § .a S"g 



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a a ^ 



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1i3 


8561 
8199 
8765 
9383 


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■s ° 
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5 iii! 111311 3 5 3!! If 




0.66 
0.608 

0.628 
0.613 

0.714 

| 0.626 

0.686 

0.61 

0.625 
0.773 


I 













s 






0.99 
0;97 
0.73 

0.74 
0.80 
0.69 
1.20 

1.12 
0.74 




I 


i 









§ 1 III s s 


ilated for ABO.-typo oompounda by S 
r, Acta Or V st. 10, 248 (1967). 
radii of B»+: Calculated from complex 
'skite compounds A(BJ,tTa„ ,)0. by F. 
metal., UACRL D910260-5, Final Re- 
July 1965. Ionio radii of B»+ : Colculat- 
•om oomplex perovskite compounds 

lated from A(Bi,B&)0, perovskite- 
oompounds. 






| 11 IlllliSls ISSIilsiS 


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